It's been 10 years since they met on the set of Mr & Mrs Smith and on Saturday August 23, 2014, Brad Pitt and Angelina Jolie finally tied the knot.
The A-list couple secretly married at Château Miraval in France with their six children, Maddox, 13, Pax, 11, Zahara, nine, Shiloh, eight, and six-year-old twins Knox and Vivienne, the guests of honour.
Now, as they begin married life by jetting to Malta to start shooting By The Sea, their first movie together in a decade, MailOnline takes a look back at one of Hollywood's greatest romances.
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Where it all began: Brad Pitt and Angelina Jolie met on the set of Mr & Mrs Smith in 2004 and the chemistry between them was sizzling even though he was married to Jennifer Aniston
No longer the perfect couple: While Brad and Jennifer Aniston's marriage was believed to be rock solid, the couple [pictured at the Emmy Awards in September 2004] announced their split in January 2005Newlyweds Brad and Angelina's best moments
May 2004: Although Brad is married to Jennifer Aniston at the time, rumours of an on-set romance swirl after Pitt and Angelina Jolie start filming Mr & Mrs Smith.More...
- BREAKING NEWS: Brad Pitt and Angelina Jolie tie the knot in secret French wedding after NINE years together
- PICTURED: Brad Pitt shows off his wedding ring for the first time after marrying Angelina Jolie in a secret French ceremony
January 2005: Brad and Jennifer announce in a joint statement that after 'much thoughtful consideration' they have decided to split.
They add: 'We happily remain committed and caring friends with great love and admiration for one another.'
A glimpse of the future: Jennifer is reportedly left heartbroken when Brad and Angelina take part in a revealing photoshoot for W magazine entitled Domestic Bliss, showing them as a couple with children
Slammed: Jennifer opens up about the devastating split and slams Brad as having a 'sensitivity chip missing' because of the W magazine shoot
March 2005: Jennifer files for divorce citing 'irreconcilable differences' as speculation about Brad and Angelina's romance continued.
April 2005: Brad and Angelina's relationship is confirmed after paparazzi photographs of them on holiday in Kenya with her son Maddox surface. They have yet to speak publicly about it.
July 2005: Jennifer is reportedly left heartbroken when Brad and Angelina take part in a revealing photoshoot for W magazine entitled Domestic Bliss. The photo essay shows them as a couple with children.
Later that month Angelina adopts her second child, daughter Zahara, from Ethiopia.
Instant family: In 2006 (when this picture of Brad, Angelina, Zahara and Maddox was taken), Brad applies to adopt the two children while Angelina announces she is expecting their first child
Happy news: The couple are pictured here in January 2006 after Angelina announced she was expecting their first child
September 2005: In Vanity Fair, Jennifer slams Brad as having a 'sensitivity chip missing' following the W photo shoot, which he brainstormed.
Regarding the pictures of them in Kenya, she adds: 'I can't say it was one of the highlights of my year,. Who would deal with that and say, "Isn't that sweet! That looks like fun?" But s**t happens. You joke and say, "What doesn't kill you makes you stronger."'
October 2005: Brad and Aniston's divorce is finalised.
Double trouble: Angelina confirms at the Cannes Film Festival premiere of Kung Fu Panda that she is expecting twins
Babies on board: In July 2008, the couple complete their family with the arrival of twins Knox and Vivienne
January 2006: Angelina and Brad announce she is pregnant with their first child while Brad applies
Charitable: Brad and Angelina sold the pictures of Knox and Vivienne to
People and HELLO! for a reported £7.5million and donated the money to
to formally adopt her children Maddox and Zahara.
May 2006: The couple's first biological child Shiloh Nouvel Jolie-Pitt is born in Swakopmund, Namibia and the couple sell the pictures to People magazine before donating the money to charity.
December 2006: Angelina tells Vogue that while filming Mr & Mrs Smith, she couldn't 'wait to get to work' to see Brad. Two years later, Jennifer brands the comments 'uncool.
March 2007: Jolie adopts three-year-old Pax Thien from Vietnam.
May 2008: At the Cannes Film Festival, Angelina confirms she is expecting twins. Knox Leon and Vivienne Marcheline are born in July.
October 2008: Angelina
reveals her romance with Brad began while he was married to Jennifer as
she says they 'fell in love' on the set of Mr & Mrs Smith. The pair
had always maintained up until this point that their relationship only
started after he split from Jennifer.
September 2011: Brad
tells Parade magazine that before Angelina he 'wasn't living an
interesting life.' He adds: 'I think that my marriage had something to
do with it, explaining that 'Trying
to pretend the marriage was something that it wasn't,' was tough.
He adds he's finally a 'satisfied man' with Angelina. He later insists the comments were misunderstood, adding: 'Jen is an incredibly giving, loving, and hilarious woman who remains my friend.'
PDA: The couple are not afraid of showing their affection in public and put on quite a show at the World War Z premiere in London in June 2013
Cheeky: In 2011 Brad couldn't resist a cheeky grab of Angelina's bum as they posed for pictures at the Golden Globes
Happier than ever: In May 2014 the couple put on yet another cosy showing as they promoted her movie Maleficent
December 2011/January 2012: The couple admit in separate interviews that their children are encouraging them to marry.
While they had planned to wait until gay marriage was legal, they reveal the pressure from the children is strong.
April 2012: Brad and Angelina reveal their engagement.
How time flies: Angelina and Brad attended the Academy Motion Picture Arts and Sciences 5th Annual Governors Awards in Los Angeles last November with Maddox, now 15
Engaged: Although Brad and Angelina [pictured at the Oscars in March] got engaged in 2012, they took two years to finally tie the knot
Family affair: Jolie and Pitt pose with their children (except for Vivienne) at the Disney premiere of Maleficent earlier this yearAngelina and Brad attend Maleficent premiere in Hollywood
February 2013: Angelina has a secret double mastectomy after discovering she had a defective BRCA-1 gene that put her at high risk of developing breast and ovarian cancers. She tells the world about it in a New York Times Op Ed in May.
July 2014: It is announced that Brad and Angelina will reunite on the big screen for the first time since Mr & Mrs Smith.. Jolie will write and direct the 'intimate, character-driven drama' By the Sea.
August 2014: The couple tie the knot in a secret ceremony at Chateau Miraval in France and after a short family honeymoon in Nice, the Jolie-Pitts head to Malta to start shooting By The Sea.
Happy family: Brad and Angelina attended the 2013 Oscars with his parents Jane and William but it is not yet known if the elder Pitts were at the wedding
Happier than ever: The couple are now the proud parents to six children, who were guests of honour at their wedding on Saturday, August 23
It's official: Brad revealed his wedding ring at a photocall for his new movie Fury in Dorset on Thursday